Molecular Formula | C2H2CuO4 |
Molar Mass | 153.58 |
Density | 1,831 g/cm3 |
Melting Point | 130°C |
Water Solubility | 12.5g/100mL H2O [CRC10]; insoluble most organic solvents [MER06] |
Storage Condition | Room Temprature |
Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R22 - Harmful if swallowed |
Safety Description | S22 - Do not breathe dust. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S60 - This material and its container must be disposed of as hazardous waste. |
invention patent
Application (patent) number:
CN201811409080.0
application date:
20181123
Public/Announcement Number:
CN109456494A
Public/announcement date:
20190312
applicant (patent):
Xi'an Technological University
inventor:
National and provincial code:
CN610112
Abstract:
The invention discloses a method for rapidly preparing amide octahedral MOFs at room temperature using copper formate as a raw material, which dissolves copper formate tetrahydrate in DMF solvent to form a salt solution, the concentration of copper formate tetrahydrate in the salt solution is 0.003~0.015mol/L; N,N & prime; N & Prime; Tris (3,5 dicarboxyphenyl) 1,3,5 tricarbamoyl benzene in DMF solvent to obtain ligand solution, ligand solution N,N & prime;,N & Prime; Tris (3,5 dicarboxyphenyl) 1,3,5 The concentration of tricarbamoyl benzene is 0.0017~0.005mol/L; An equal volume of ligand solution is added to the salt solution, and the reaction is allowed to stand until a blue precipitate is produced in the solution, A solution containing an amide-type octahedral MOFs material is obtained; The solution containing an amide-type octahedral MOFs material is centrifuged and washed to obtain an amide-type octahedral MOFs material; the method of the invention can be prepared at room temperature
Liu Ziru , Kong Yanhui Yin Cui Mei , Wu Chengyun
Abstract:
The thermal decomposition process of copper benzoate and its three amino derivatives were studied by TG and DSC: their decomposition reaction can produce one or two more stable dimer intermediate products-binuclear copper complex, decarboxylation and rearrangement process is the main step of decomposition, the fastest process. During the whole decomposition process, the endothermic substituents and their positions on the benzene ring affect the decomposition process. In addition, the kinetic parameters of the rapid decomposition stage of copper ortho-and M-aminobenzyl alcohol were also determined.
Key words:
combustion catalyst; Benzoate; Thermal decomposition
DOI:
CNKI:SUN:GTHJ.0.1997-01-009
cited:
year:
1997
Zhao Yaling , du Rongbin , Li Yan
Abstract:
The large particle single crystal of hydrogen copper benzoate was synthesized by rheological phase reaction method. The composition and crystal structure were characterized by elemental analysis and four-circle single crystal diffraction analysis: copper benzoate is monoclinic, space group P21/n,a = 1.079 9(2)am,6=1.178 0(2)nm,c = 1.530 3(3)nm, Β = 91.35(3)°,V = 1.946 1(7)nm3,Z = 4,& rho;calc = 1.460,& rho;exp = 1.455 s/cm3.μ = 1.156-1,F(000)= 876,s = 0.990, final deviation factor R = 0.056 0 and wR = 0.075 0[I>2 & sigma;(I)]. The magnetic susceptibility of the Crystal was measured by a magnetic balance. The close relationship between the particle size of the reactants and the grain size of the growing single crystals was studied by means of scanning electron microscopy. The chemical reaction mechanism and the single crystal growth mechanism in the rheological phase system were discussed, molecular recognition and self-assembly were found in the rheological phase system.
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Key words:
rheological phase synthesis aromatic carboxylates complex crystal growth
DOI:
10.3969/j.issn.1671-3206.2011.01.025
cited:
year:
2011